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Haas PA Begovich JM Ryon AD Vavruska JS (1980) Chemical flowsheet conditions for preparing urania spheres by internal gelation. Ind Eng Chem Prod Res Dev 19(3) 459 Google Scholar
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Mar 02 1998 · A new method for preparing the broth for internal gelation without cooling was developed and it was applied to UO 2 microsphere preparation. The broth was prepared by mixing two components just before drop formation one was an uranyl nitrate solution and the other a hexamethylenetetramine solution.
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Additional gelation-based processes for producing ceramic balls have been reported. Haas et al Chemical Flowsleet Conditions for Preparing Urania Spheres by Internal Gelation I EC Product Res. Dev. 19(3) 459-67 (1980) produced UO 2 balls by chemical gelation of uranyl nitrate solution
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Previously established flowsheet conditions have been improved and modified at ORNL and have been applied to prepare dense UO//2 spheres with average diameters of 1200 300 and 30 mu m.
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Ethylene oxide is an organic compound with the formula C 2 H 4 O is a cyclic ether and the simplest epoxide a three-membered ring consisting of one oxygen atom and two carbon atoms.Ethylene oxide is a colorless and flammable gas with a faintly sweet odor. Because it is a strained ring ethylene oxide easily participates in a number of addition reactions that result in ring-opening.
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Mar 01 2013 · Though the process steps are similar for various types of microspheres there are significant variations due to the chemical nature of metal ions. It was expected that the process flowsheet to prepare (U 0.47 Pu 0.53)O 2 will be different from other actinides due to unique solution chemistry of plutonium. A number of important modifications
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Chemical Flowsheet Conditions for Preparing Urania Spheres by Internal Gelation. Paul A. Haas John M. Begovich Allen D. Ryon and Recommended dispersing conditions for broths used in the preparation of uranium microspheres with carbon. State and tendency of developing physical-chemical methods for making actinide microspherical
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For the UO3 center dot 2H (2)O microspheres with and without carbon dehydration occurred at the same rate. The dehydration was accompanied by spontaneous reduction of the urania to UO2.67. In the
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Low density porous metal oxide microspheres are prepared from metal salt solutions by sol-gel technique followed by ammonia treatment of the green microspheres drying impregnation with fugitive organic material and heat temperature under controlled conditions of temperature and atmosphere. The product metal oxide microspheres have a density of below 70 of their theoretical maximum density
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Ethylene oxide is an organic compound with the formula C 2 H 4 O is a cyclic ether and the simplest epoxide a three-membered ring consisting of one oxygen atom and two carbon atoms.Ethylene oxide is a colorless and flammable gas with a faintly sweet odor. Because it is a strained ring ethylene oxide easily participates in a number of addition reactions that result in ring-opening.
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Mar 02 1998 · A new method for preparing the broth for internal gelation without cooling was developed and it was applied to UO 2 microsphere preparation. The broth was prepared by mixing two components just before drop formation one was an uranyl nitrate solution and the other a hexamethylenetetramine solution.
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(e> the dasng paste was shaken for a few minutes duking which time it liquefied to form a fbirly vfscous sol containing about 0.4-0.5 Mmetal and a residual nitrate concentration of about 0.04 1 (for Eu and the heavier lanthaslides) to 0.1 M(for the lower lanthanides). for 1 to 2 hr at 8OoC during which the the initially amorphous colloid l particles were convelrted to crJrstdhe
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Small ceramic urania spheres can be prepared for use as nuclear fuel by internal chemical gelation of uranyl nitrate solution droplets. Decomposition of hexamethylenetetramine (HMTA) dissolved in the uranyl nitrate solution releases ammonia to precipitate hydrated UO/sub 3/.
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In this type of chemical reaction the monomers that are present contain reacting end groups. Specifically a diisocyanate (OCN-R-NCO) is reacted with a diol (HO-R-OH). The first step of this reaction results in the chemical linking of the two molecules leaving a reactive alcohol (OH) on one side and a reactive isocyanate (NCO) on the other.
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Research on pebble bed HTR fuel fabrication is conducted in Indonesia. One of the aims is to build a knowledge base on pebble bed HTR fuel element fabrication technology for fuel procurement. The steps of research strategies are firstly to understand the basic design research of TRISO fuel properties and requirements and secondly to understand the TRISO fuel manufacturing technology which
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The product spheres allow good measurements of the drop size distributions. The basic technique re- optimum conditions the drop formation is so regular that Haas P. A. et al. Chemical Flowsheet Conditions for Preparing Urania Spheres by Internal Gelation. Id. Eng. Chem. Rod. Res. Dev. 1980 19 .
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Chemical flowsheet conditions for preparing urania spheres by internal gelation Technical Report Haas P A Begovich J M Ryon A D Small ceramic urania spheres can be prepared for use as nuclear fuel by internal chemical gelation of uranyl nitrate solution droplets.
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Aug 03 2007 · Journal of the American Chemical Society. Molecule-Like Eu3 -Dimers Embedded in an Extended System Exhibit Unique Photoluminescence Properties. Industrial Engineering Chemistry Product Research and Development. Chemical Flowsheet Conditions for Preparing Urania Spheres by Internal Gelation. The Journal of Physical Chemistry A
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Mar 27 2017 · Haas PA Begovich JM Ryon AD Vavruska JS (1980) Chemical flowsheet conditions for preparing urania spheres by internal gelation. Ind Eng Chem Prod Res Dev 19 459–467. doi 10.1021/i360075a033 Article Google Scholar
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Nov 17 2020 · This chapter covers different types of chemical process diagrams how these diagrams represent different scales of process views one consistent method for drawing process flow diagrams the information to be included in a process flow diagram and the purpose of operator training simulators and recent advances in 3-D representation of different chemical processes.
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flowsheet conditions have been reported by other laboratories. 9-11 Im- provements and modifications to previously published flowsheet condition7 p8 for the internal chemical gelation process were developed and reported at ORNL2 to prepare dense U02 spheres with average diameters of
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Haas PA Begovich JM Ryon AD Vavruska JS (1980) Chemical flow sheet conditions for preparing urania spheres by internal gelation. Ind Eng Chem Prod
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Complex polymers are distributed in more than one direction of molecular heterogeneity. In addition to the molar mass distribution they are frequently distributed with respect to chemical composition functionality and molecular architecture. For the characterization of the different types of molecular heterogeneity it is necessary to use a wide range of analytical techniques. Preferably
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